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钾掺杂的石墨相氮化碳可实现高效可见光驱动的染料降解。

Potassium-doped g-CN enables efficient visible-light-driven dye degradation.

作者信息

Yuan Lianxin, Liu Weixuan, Zhang Wanting

机构信息

Hubei Provincial Ecological Environment Monitoring Center Station, No. 338, Bayi Road, Wuhan, 430070, China.

Hubei Provincial Department of Ecology and Environment, Suizhou Ecological Environment Monitoring Center, No. 168 Yanhe Avenue, Suizhou, 441399, China.

出版信息

Environ Sci Pollut Res Int. 2023 Apr;30(20):58276-58281. doi: 10.1007/s11356-023-26520-5. Epub 2023 Mar 28.

Abstract

Element doping is recognized as an efficient method to boost the photocatalytic performance of photocatalysts. Here, a new potassium ion-doped precursor, potassium sorbate, was employed in melamine configuration during calcination process to prepare the potassium-doped g-CN (KCN). By various characterization techniques and electrochemical measurements, the doping of K in g-CN can efficiently modify the band structure to enhance the light absorption and greatly increase the conductivity to accelerate charge transfer and photogenerated carrier separation, ultimately achieving an excellent photodegradation of the organic pollutant (methylene blue, MB). These results have demonstrated that the approach of potassium incorporation in g-CN has potential in fabricating high-performance photocatalysts for organic pollutant removal.

摘要

元素掺杂被认为是提高光催化剂光催化性能的有效方法。在此,一种新的钾离子掺杂前驱体山梨酸钾在煅烧过程中以三聚氰胺构型被用于制备钾掺杂的g-CN(KCN)。通过各种表征技术和电化学测量,g-CN中钾的掺杂可以有效地改变能带结构以增强光吸收,并大大提高电导率以加速电荷转移和光生载流子分离,最终实现对有机污染物(亚甲基蓝,MB)的优异光降解。这些结果表明,在g-CN中掺入钾的方法在制备用于去除有机污染物的高性能光催化剂方面具有潜力。

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