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通过一步水热法用橙汁绿色合成碳量子点,用于多巴胺的快速、准确检测。

The Green Synthesis of Carbon Quantum Dots through One-step Hydrothermal Approach by Orange Juice for Rapid, and Accurate Detection of Dopamine.

机构信息

Nanotechnology Research Institute, School of Chemical Engineering, Babol Noshirvani University of Technology, Babol, Iran.

School of Mechanical and Materials Engineering, Washington State university, Pullman, WA, USA.

出版信息

J Fluoresc. 2024 Nov;34(6):2665-2677. doi: 10.1007/s10895-023-03483-x. Epub 2023 Oct 26.

Abstract

In the current study, the fluorescent Carbon quantum dots (CDs) were synthesized through one-step hydrothermal approach by orange juice without any additional agents. The as-prepared green-CDs (GCDs) were quasi-spherical shape ranged from 2 to 8 nm with an average diameter of 5 nm, and emitted bright blue fluorescent (FL) under ultraviolet light irradiation (Uv). Different detailed analyses proved that the as-prepared GCDs had good morphologies, various functional groups, high water solubility, great optical features, and excellent stability towards diverse environmental conditions. The results indicated that the as-prepared GCDs can detect different concentrations of dopamine from 1 to 100 µM based on the quenching of their native fluorescent. Furthermore, the good linear relationship was obtained for dopamine in the broad range of concentrations from 1 to 100 µM with the limit of detection (LOD) of 0.81 µM. In addition, the as-prepared GCDs can be applied as a fluorescent probe for detection of dopamine in the different real samples.

摘要

在本研究中,通过一步水热法,以橙汁为原料,无需添加任何其他试剂,合成了荧光碳量子点(CDs)。所制备的绿色-CDs(GCDs)呈类球形,尺寸为 2-8nm,平均直径为 5nm,在紫外光照射下发出明亮的蓝色荧光(FL)。不同的详细分析证明,所制备的 GCDs 具有良好的形态、多种官能团、高水溶性、优异的光学性能和对各种环境条件的优异稳定性。结果表明,所制备的 GCDs 可以基于其本征荧光的猝灭来检测 1-100µM 不同浓度的多巴胺。此外,在 1-100µM 的宽浓度范围内,多巴胺得到了良好的线性关系,检测限(LOD)为 0.81µM。此外,所制备的 GCDs 可以用作荧光探针,用于检测不同实际样品中的多巴胺。

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