功能化烷基硅基过氧化物在铁催化及可见光促进的自由基转化中的合成应用
Synthetic utility of functionalized alkylsilyl peroxides for Fe-catalyzed and visible-light-promoted radical transformation.
作者信息
Liu Jiahao, Liu Shiyong, Wang Zhe, Kato Terumasa, Liu Yan, Maruoka Keiji
机构信息
School of Chemical Engineering and Light Industry, Guangdong University of Technology Guangzhou 510006 China
Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangdong University of Technology Guangzhou 510006 China.
出版信息
Chem Sci. 2024 Feb 22;15(13):4757-4762. doi: 10.1039/d3sc06857a. eCollection 2024 Mar 27.
Abstract
α-Keto-, β-acetoxy- and β-amidoalkylsilyl peroxides are prepared from various precursors and utilized for Fe-catalyzed and visible-light-promoted radical functionalization with coupling partners under mild conditions with a broad substrate scope.
摘要
α-酮基、β-乙酰氧基和β-氨基烷基甲硅烷基过氧化物由各种前体制备而成，并用于在温和条件下、底物范围广泛的情况下，与偶联伙伴进行铁催化和可见光促进的自由基官能化反应。
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