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采用固态法合成的 Pb(PO)Br:RE(RE = Dy、Eu 和 Tb)荧光粉的光致发光性能。

Photoluminescence properties of Pb(PO)Br:RE (RE = Dy, Eu and Tb) phosphor synthesised using solid-state method.

机构信息

Department of Electronics, Bajaj College of Science, Wardha, India.

Department of Physics, RTM Nagpur University, Nagpur, India.

出版信息

Luminescence. 2024 May;39(5):e4751. doi: 10.1002/bio.4751.

Abstract

This study describes the luminous properties of Pb(PO)Br doped with RE (RE = Dy, Eu and Tb) synthesised using the solid-state method. The synthesised phosphor was characterised using Fourier-transform infrared, X-ray diffraction, scanning electron microscopy and photoluminescence measurements. Dy-doped Pb(PO)Br phosphor exhibited blue and yellow emissions at 480 and 573 nm, respectively, on excitation at 388 nm. Eu-doped Pb(PO)Br phosphor exhibited orange and red emissions at 591 and 614 nm, respectively, on excitation at λ = 396 nm. Pb(PO)Br:Tb phosphor exhibited the strongest green emission at 547 nm on excitation at λ = 380 nm. Additionally, the effect of the concentration of rare-earth ions on the emission intensity of Pb(PO)Br:RE (RE = Dy, Eu and Tb) phosphors was investigated.

摘要

本研究描述了采用固态法合成的掺杂 RE(RE=Dy、Eu 和 Tb)的 Pb(PO)Br 的发光特性。通过傅里叶变换红外、X 射线衍射、扫描电子显微镜和光致发光测量对合成的荧光粉进行了表征。在 388nm 激发下,Dy 掺杂的 Pb(PO)Br 荧光粉分别在 480nm 和 573nm 处显示蓝色和黄色发射。Eu 掺杂的 Pb(PO)Br 荧光粉在λ=396nm 激发下分别在 591nm 和 614nm 处显示橙色和红色发射。在λ=380nm 激发下,Pb(PO)Br:Tb 荧光粉表现出最强的绿色发射,位于 547nm。此外,还研究了稀土离子浓度对 Pb(PO)Br:RE(RE=Dy、Eu 和 Tb)荧光粉发射强度的影响。

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