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负载MXene@g-CN的碳纳米纤维膜:制备及其光催化性能

Carbon Nanofiber Membranes Loaded with MXene@g-CN: Preparation and Photocatalytic Property.

作者信息

Lou Ching-Wen, Xie Meng-Meng, Yang Yan-Dong, Wang Hong-Yang, Wang Zhi-Ke, Zhang Lu, Hsieh Chien-Teng, Liu Li-Yan, Lin Mei-Chen, Li Ting-Ting

机构信息

Innovation Platform of Intelligent and Energy-Saving Textiles, School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.

Department of Bioinformatics and Medical Engineering, Asia University, Taichung 413305, Taiwan.

出版信息

Nanomaterials (Basel). 2024 May 20;14(10):896. doi: 10.3390/nano14100896.

Abstract

In this study, a TiC MXene@g-CN composite powder (TM-CN) was prepared by the ultrasonic self-assembly method and then loaded onto a carbon nanofiber membrane by the self-assembly properties of MXene for the treatment of organic pollutants in wastewater. The characterization of the TM-CN and the C-TM-CN was conducted via X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectrometer (FTIR) to ascertain the successful modification. The organic dye degradation experiments demonstrated that introducing an appropriate amount of TiC MXene resulted in the complete degradation of RhB within 60 min, three times the photocatalytic efficiency of a pure g-CN. The C-TM-CN exhibited the stable and outstanding photocatalytic degradation of the RhB solution over a wide range of pH values, indicating the characteristics of the photodegradation of organic pollutants in a wide range of aqueous environments. Furthermore, the results of the cyclic degradation experiments demonstrated that the C-TM-CN composite film maintained a degradation efficiency of over 85% after five cycles, thereby confirming a notable improvement in its cyclic stability. Consequently, the C-TM-CN composite film exhibits excellent photocatalytic performance and is readily recyclable, making it an auspicious eco-friendly material in water environment remediation.

摘要

在本研究中,通过超声自组装法制备了TiC MXene@g-CN复合粉末(TM-CN),然后利用MXene的自组装特性将其负载到碳纳米纤维膜上,用于处理废水中的有机污染物。通过X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)和傅里叶变换红外光谱仪(FTIR)对TM-CN和C-TM-CN进行表征,以确定改性是否成功。有机染料降解实验表明,引入适量的TiC MXene可使RhB在60分钟内完全降解,光催化效率是纯g-CN的三倍。C-TM-CN在较宽的pH值范围内对RhB溶液表现出稳定且出色的光催化降解性能,表明其在广泛的水环境中对有机污染物具有光降解特性。此外,循环降解实验结果表明,C-TM-CN复合膜在五个循环后仍保持超过85%的降解效率,从而证实其循环稳定性有显著提高。因此,C-TM-CN复合膜具有优异的光催化性能且易于回收,是水环境修复中一种有前景的环保材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc19/11124281/5df3b22e8351/nanomaterials-14-00896-g001.jpg

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