State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200241, China.
Yangtze Delta Estuarine Wetland Ecosystem Observation and Research Station, Ministry of Education & Shanghai Science and Technology Committee, Shanghai 200241, China.
Environ Sci Technol. 2024 Jun 18;58(24):10776-10785. doi: 10.1021/acs.est.4c01031. Epub 2024 Jun 5.
Rivers have been recognized as the primary conveyors of microplastics to the oceans, and seaward transport flux of riverine microplastics is an issue of global attention. However, there is a significant discrepancy in how microplastic concentration is expressed in field occurrence investigations (number concentration) and in mass flux (mass concentration). Of urgent need is to establish efficient conversion models to correlate these two important paradigms. Here, we first established an abundant environmental microplastic dataset and then employed a deep neural residual network (ResNet50) to successfully separate microplastics into fiber, fragment, and pellet shapes with 92.67% accuracy. We also used the circularity () parameter to represent the surface shape alteration of pellet-shaped microplastics, which always have a more uneven surface than other shapes. Furthermore, we added thickness information to two-dimensional images, which has been ignored by most prior research because labor-intensive processes were required. Eventually, a set of accurate models for microplastic mass conversion was developed, with absolute estimation of 7.1, 3.1, 0.2, and 0.9% for pellet (0.50 ≤ < 0.75), pellet (0.75 ≤ ≤ 1.00), fiber, and fragment microplastics, respectively; environmental samples have validated that this set is significantly faster (saves ∼2 h/100 MPs) and less biased (7-fold lower estimation errors) compared to previous empirical models.
河流已被公认为是向海洋输送微塑料的主要载体,而河流向海洋输送微塑料的通量是一个备受全球关注的问题。然而,在实地调查中,微塑料浓度的表示方式(数量浓度)和质量通量(质量浓度)之间存在显著差异。因此,迫切需要建立有效的转换模型来关联这两个重要的研究范式。在这里,我们首先建立了一个丰富的环境微塑料数据集,然后使用深度神经网络(ResNet50)成功地将微塑料分为纤维、碎片和颗粒形状,准确率为 92.67%。我们还使用了圆度()参数来表示颗粒状微塑料表面形状的变化,因为颗粒状微塑料的表面通常比其他形状更不规则。此外,我们还在二维图像中添加了厚度信息,这一点在大多数先前的研究中都被忽略了,因为这需要进行劳动密集型的处理过程。最终,我们开发了一套准确的微塑料质量转换模型,对于粒径为 0.50≤<0.75、0.75≤<1.00、纤维和碎片的颗粒微塑料,其绝对估计误差分别为 7.1%、3.1%、0.2%和 0.9%;环境样本验证表明,与之前的经验模型相比,该模型速度更快(节省约 2 小时/100 个 MPs),偏差更小(估计误差降低了 7 倍)。