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硼氢化钠煅烧磁性锰铁氧体纳米颗粒的光催化活性增强

Enhanced Photocatalytic Activities of Sodium Borohydride-Calcined Magnetic Manganese Ferrite Nanoparticles.

作者信息

Hoang Dung Thanh, Pham Vy Ngoc, Yu Hyejin, Kwak In Hye, Baik Jaeyoon, Kim Hyun Sung, Lee Hangil

机构信息

Department of Chemistry, Sookmyung Women's University, Seoul 04310, Republic of Korea.

Department of Chemistry, Pukyong National University, Busan 48513, Republic of Korea.

出版信息

Inorg Chem. 2024 Jul 1;63(26):12054-12062. doi: 10.1021/acs.inorgchem.4c00993. Epub 2024 Jun 13.

Abstract

The synthesis, enhancement, and maintenance of magnetite-based catalyst nanoparticles (NPs) are important for photocatalytic activity and recovery rates. We used a sodium borohydride (NaBH) calcination method to modify MnFeO nanoparticles to optimize their performance in the photocatalytic oxidation of 2,5-hydroxymethylfurfural. The results indicated a 94% increase in photocatalytic efficiency, while magnetic assessments performed using a vibrating sample magnetometer showed an 8.9% improvement in magnetic properties without degradation. These findings show the dual benefits of increased photocatalytic performance with strong magnetic properties, which are important for the application and reusability of photocatalysts. The recycling of these photocatalysts reduces secondary pollution and increases the process cost-effectiveness. These results contribute to the solution of problems with the use of photocatalytic materials.

摘要

基于磁铁矿的催化剂纳米颗粒(NPs)的合成、增强和维持对于光催化活性和回收率很重要。我们使用硼氢化钠(NaBH)煅烧方法对MnFeO纳米颗粒进行改性,以优化其在2,5-羟甲基糠醛光催化氧化中的性能。结果表明光催化效率提高了94%,而使用振动样品磁强计进行的磁性评估显示磁性性能提高了8.9%且无降解。这些发现表明了光催化性能增强与强磁性的双重益处,这对于光催化剂的应用和可重复使用性很重要。这些光催化剂的回收利用减少了二次污染并提高了工艺成本效益。这些结果有助于解决光催化材料使用中的问题。

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