Miller Katie E, Jahn Ann-Carolin, Strohm Brian M, Demyttenaere Shao M, Nikolai Paul J, Behm Byron D, Paracha Mariam S, Miri Massoud J
School of Chemistry and Materials Science, Rochester Institute of Technology, Rochester, NY 14623, USA.
National Technical Institute for the Deaf, Rochester Institute of Technology, Rochester, NY 14623, USA.
Polymers (Basel). 2025 Mar 30;17(7):937. doi: 10.3390/polym17070937.
By 2050, 700 million people will have hearing loss, requiring rehabilitation services. For about 80% of deaf and hard-hearing individuals, face coverings hinders their ability to lip-read. Also, the normal hearing population experiences issues socializing when wearing face masks. Therefore, there is a need to evaluate and further develop transparent face masks. In this work, the properties of polymers used in ten commercial transparent face masks were determined. The chemical composition of the polymers including nose bridges and ear loops was determined by FTIR spectroscopy. The focus of the characterizations was on the polymers in the transparent portion of each face mask. In half of the masks, the transparent portion contained PET, while in the other masks it consisted of PETG, PC, iPP, PVC, or SR (silicone rubber). Most masks had been coated with anti-fog material, and a few with scratch-resistant compounds, as indicated by XRF/EDX, SEM/EDX, and contact angle measurements. Thermal, molecular weight, and mechanical properties were determined by TGA/DSC, SEC, and tensile tests, respectively. To measure optical properties, UV-Vis reflectance and UV-Vis haze were applied. An assessment of the ten masks and recommendations to develop better transparent face masks were made, including improvement of their sustainability.
到2050年,将有7亿人听力受损,需要康复服务。对于约80%的聋人和听力障碍者来说,面部覆盖物会妨碍他们唇读。此外,听力正常的人在佩戴口罩时也会遇到社交问题。因此,有必要评估并进一步开发透明口罩。在这项工作中,测定了十种商用透明口罩中使用的聚合物的性能。通过傅里叶变换红外光谱法测定了包括鼻梁和耳挂在内的聚合物的化学成分。表征的重点是每个口罩透明部分的聚合物。在一半的口罩中,透明部分含有聚对苯二甲酸乙二酯(PET),而在其他口罩中,它由聚对苯二甲酸乙二醇酯二醇改性共聚酯(PETG)、聚碳酸酯(PC)、等规聚丙烯(iPP)、聚氯乙烯(PVC)或硅橡胶(SR)组成。如X射线荧光光谱/能量色散X射线光谱(XRF/EDX)、扫描电子显微镜/能量色散X射线光谱(SEM/EDX)和接触角测量所示,大多数口罩都涂有防雾材料,少数涂有抗划伤化合物。热性能、分子量和机械性能分别通过热重分析/差示扫描量热法(TGA/DSC)、尺寸排阻色谱法(SEC)和拉伸试验来测定。为了测量光学性能,采用了紫外可见反射率和紫外可见雾度。对这十种口罩进行了评估,并提出了开发更好的透明口罩的建议,包括提高其可持续性。