Gel-Based Self-Powered Nanogenerators: Materials, Mechanisms, and Emerging Opportunities.

With the rapid rise in Internet of Things (IoT) and artificial intelligence (AI) technologies, there is an increasing need for portable, wearable, and self-powered flexible sensing devices. In such scenarios, self-powered nanogenerators have emerged as promising energy harvesters capable of converting ambient mechanical stimuli into electrical energy, enabling the development of autonomous flexible sensors and sustainable systems. This review highlights recent advances in nanogenerator technologies-particularly those based on piezoelectric and triboelectric effects-with a focus on soft, flexible, and gel-based polymer materials. Key mechanisms of energy conversion are discussed alongside strategies to enhance performance through material innovation, structural design, and device integration. Special attention is given to the role of gel-type composites, which offer unique advantages such as mechanical tunability, self-healing ability, and biocompatibility, making them highly suitable for next-generation wearable, biomedical, and environmental sensing applications. We also explore the evolving landscape of energy applications, from microscale sensors to large-area systems, and identify critical challenges and opportunities for future research. By synthesizing progress across materials, mechanisms, and application domains, this review aims to guide the rational design of high-performance, sustainable nanogenerators for the next era of energy technologies.