对来自爵床的三种新芳基萘木脂素的¹H和¹³C NMR数据进行完整归属。

Complete assignments of 1H and 13C NMR data for three new arylnaphthalene lignan from Justicia procumbens.

作者信息

Liu Guorui, Wu Jun, Si Jianyong, Wang Junmei, Yang Meihua

机构信息

Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100094, P.R. China.

出版信息

Magn Reson Chem. 2008 Mar;46(3):283-6. doi: 10.1002/mrc.2175.

DOI:10.1002/mrc.2175

PMID:18236441

Abstract

Three new arylnaphthalene lignans, named neojusticin C (1), procumbenoside C (2) and procumbenoside D (3), have been isolated from the whole plant of Justicia procumbens, together with three known ones, justicidinoside B (4), justicidinoside C (5), and diphyllin-1-O-beta-D-apiofuranoside (6). The complete assignments of 1H and 13C NMR data for three new lignans were first obtained by means of 2D NMR techniques, including HSQC and HMBC.

摘要

从爵床全草中分离出三种新的芳基萘木脂素，分别命名为新爵床苷C（1）、匍匐苷C（2）和匍匐苷D（3），以及三种已知的木脂素，爵床苷B（4）、爵床苷C（5）和双叶豆素-1-O-β-D-芹菜呋喃糖苷（6）。借助二维核磁共振技术，包括异核单量子相干谱（HSQC）和异核多键相关谱（HMBC），首次完成了三种新木脂素的氢谱（1H NMR）和碳谱（13C NMR）数据的全归属。