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负载金属的纳米二氧化钛在 2-丙醇悬浮液中,在溶解的氢氧化钠存在的条件下,光催化还原脱氯氯苯为苯。

Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide.

机构信息

Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashiosaka, Osaka 577-8502, Japan.

出版信息

Chem Commun (Camb). 2010 Jul 28;46(28):5118-20. doi: 10.1039/c0cc00589d. Epub 2010 Jun 11.

Abstract

Photocatalytic reaction of chlorobenzene in 2-propanol suspension of palladium- and rhodium-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide under deaerated conditions, in which 2-propanol, metal loaded (palladium and rhodium) and sodium hydroxide effectively acted as hole scavenger, co-catalyst and chloride solidifier, respectively, quantitatively gave benzene and chloride ions with a high stoichiometry.

摘要

在无氧条件下,负载钯和铑的纳米二氧化钛在 2-丙醇悬浮液中的光催化反应,其中 2-丙醇、负载金属(钯和铑)和氢氧化钠分别有效地作为空穴清除剂、助催化剂和氯离子稳定剂,定量地得到高化学计量比的苯和氯离子。

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