Clermont Université, Laboratoire SEESIB, BP 10448, F-63000, Clermont-Ferrand, France.
Dalton Trans. 2010 Aug 14;39(30):7091-7. doi: 10.1039/c002982c. Epub 2010 Jun 25.
4-Triazolyl-dipicolinic acids, prepared efficiently by CuAAC, proved to act as efficient antennae for optical lanthanide probes containing Eu(3+) or Tb(3+), under linear and non linear excitations (one, two and three photons provided by laser induced luminescence). The versatility offered by the substitution of the triazole subunit is, in addition, useful for covalent linkage to slide glass providing luminescent films.
4-三唑基-二吡啶酸,通过铜催化的叠氮-炔环加成反应(CuAAC)高效制备,证明作为含有 Eu(3+)或 Tb(3+)的光学镧系探针的有效天线,在线性和非线性激发下(通过激光诱导发光提供一个、两个和三个光子)。三唑取代基提供的多功能性对于与载玻片的共价连接也很有用,从而提供了发光薄膜。