Department of Chemistry, Dmitri Mendeleev Block, Indian Institute of Science Education and Research, Pune, India.
Analyst. 2012 Sep 7;137(17):3921-4. doi: 10.1039/c2an35524h. Epub 2012 Jul 3.
A BODIPY-based selective thiophenol probe capable of discriminating aliphatic thiols is reported. The fluorescence off-on effect upon reaction with thiol is elucidated with theoretical calculations. The sensing of thiophenol is associated with a color change from red to yellow and 63-fold enhancement in green fluorescence. Application of the probe for selective thiophenol detection is demonstrated by live cell imaging.
报道了一种基于 BODIPY 的选择性硫酚探针,能够区分脂肪族硫醇。通过理论计算阐明了与硫醇反应时的荧光关闭-开启效应。与硫酚的传感相关的是颜色从红色变为黄色,并且绿色荧光增强了 63 倍。通过活细胞成像证明了该探针用于选择性硫酚检测的应用。