基于罗丹明 B 衍生物的新型系列比色和荧光化学传感器用于 Fe3+。
A novel series colorimetric and off-on fluorescent chemosensors for Fe3+ based on rhodamine B derivative.
机构信息
Phosphorus Chemical Engineering Research Center of Henan Province, Key Laboratory of Chemical Biology, Zhengzhou University, Zhengzhou, China.
出版信息
J Fluoresc. 2013 Jan;23(1):13-9. doi: 10.1007/s10895-012-1118-1. Epub 2012 Aug 18.
A novel series colorimetric and off-on fluorescent chemosensors (2a, 2b, 2c) were designed and synthesized, which showed reversible and highly selective and sensitive recognition toward Fe(3+) over other examined metal ions. Upon addition of Fe(3+), sensors (2a, 2b) exhibit remarkably and 2c exhibits moderate enhanced absorbance intensity and color change from colorless to pink in CH(3)OH-H(2)O(1:1, v/v). The three compounds (2a, 2b, 2c) may therefore be applicable as rhodamine-based turn-on type fluorescent chemosensors.
设计并合成了一系列新型的比色和荧光化学传感器（2a、2b、2c），它们对 Fe(3+)具有可逆的、高度选择性和灵敏的识别能力，而对其他测试的金属离子则没有。加入 Fe(3+)后，传感器（2a、2b）在 CH(3)OH-H(2)O(1:1,v/v)中表现出显著的、2c 则表现出适度增强的吸收强度和颜色变化，从无色变为粉红色。因此，这三种化合物（2a、2b、2c）可以作为基于罗丹明的荧光化学传感器。
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