一种基于查尔酮的三价金属阳离子高选择性和高灵敏度的显色荧光探针。
A Chalcone-Based Highly Selective and Sensitive Chromofluorogenic Probe for Trivalent Metal Cations.
作者信息
Santos-Figueroa Luis E, Llopis-Lorente Antoni, Royo Santiago, Sancenón Félix, Martínez-Máñez Ramón, Costero Ana M, Gil Salvador, Parra Margarita
机构信息
Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia, Camino de Vera, s/n, 46022 Valencia (Spain).
Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera, s/n, 46022 Valencia (Spain).
出版信息
Chempluschem. 2015 May;80(5):800-804. doi: 10.1002/cplu.201500042. Epub 2015 Feb 23.
A new chalcone-based probe for the chromofluorogenic sensing of trivalent (Al , Fe , Cr , Ga , In and As ) over mono- and divalent cations and anions is reported. In the presence of trivalent metal cations, the probe was able to display a remarkable color change from yellow to colorless that was clearly visible to the naked eye. Also, the initial strong yellow emission was gradually quenched and substituted by a weakly shifted band.
报道了一种基于查尔酮的新型探针，用于对三价阳离子（铝、铁、铬、镓、铟和砷）相对于一价和二价阳离子及阴离子进行发色荧光传感。在三价金属阳离子存在下，该探针能够呈现出从黄色到无色的显著颜色变化，肉眼清晰可见。此外，最初强烈的黄色发射逐渐猝灭，并被一个微弱位移的谱带所取代。
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