一种单（杯[4]芳烃）取代的BODIPY传感器通过二聚体化逆转对汞的非常规开-关响应。
Unconventional OFF-ON Response of a Mono(calix[4]arene)-Substituted BODIPY Sensor for Hg through Dimerization Reversion.
作者信息
Lorente Alejandro, Ochoa Andres, Rodriguez-Lavado Julio, Rodriguez-Nuévalos Silvia, Jaque Pablo, Gil Salvador, Sáez José A, Costero Ana M
机构信息
Departamento de Química Orgánica y Fisicoquímica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Olivos 1007, 8380492 Independencia, Santiago, Chile.
Institut für Chemie und Biochemie, Freie Universität Berlin, Arminallee 22, 14195 Berlin, Germany.
出版信息
ACS Omega. 2022 Dec 23;8(1):819-828. doi: 10.1021/acsomega.2c06161. eCollection 2023 Jan 10.
A new selective fluorogenic chemosensor for Hg, which combines a calixarene derivative with a BODIPY core as a fluorescent reporter, is described. The remarkable change in its fluorogenic properties in DMSO and CHCl has been analyzed. A study of its spectral properties on dilution, along with molecular modeling studies, allowed us to explain that this behavior involves the formation of a J-dimer, as well as how the sensing mechanism of Hg proceeds.
描述了一种新型的汞选择性荧光化学传感器，它将杯芳烃衍生物与作为荧光报告基团的BODIPY核心相结合。分析了其在二甲基亚砜（DMSO）和氯仿（CHCl）中荧光性质的显著变化。对其稀释时的光谱性质进行研究，并结合分子模拟研究，使我们能够解释这种行为涉及J-二聚体的形成，以及汞的传感机制是如何进行的。
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