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具有低压降的抗菌和防污空气过滤器的简便纳米结构氧化锌涂层技术。

Facile nanostructured zinc oxide coating technique for antibacterial and antifouling air filters with low pressure drop.

机构信息

Department of Nano-Bio Convergence, Korea Institute of Materials Science (KIMS), Changwon 51508, South Korea.

出版信息

J Colloid Interface Sci. 2022 Apr 15;612:496-503. doi: 10.1016/j.jcis.2021.12.139. Epub 2021 Dec 29.

Abstract

Air filters effectively filtrate external contaminants including pathogenic bioaerosols; however, they also act as culture sites for the pathogenic bacteria captured in nutrient organic pollutants. Although many researchers have applied various antibacterial coatings to filters, the coating application inevitably increased the pressure drop, leading to the low efficiency and high energy consumption of the purification system. Herein, we report a simple nanostructured zinc oxide (ZnO) coating technique to confer a polypropylene nonwoven filter with superior antibacterial, antifouling and anti-biofilm properties without an additional pressure drop. For aerodynamic coating designs, filters were directly immersed into low concentration precursor solutions to enable the sedimentation of the ZnO sol-gel particles on the filter fibers according to fluid dynamic. The precursor concentration affected the surface topology and so properties of the as-fabricated coating. 0.07 M precursor solution produced a rose-like nanostructured coating exhibiting no pressure-drop increase. The large specific surface area and hydrophobic surface killed and then repelled the attached bacteria effectively. As a result, the bare filter promoted the growth and consequent biofilm formation of the surface bacteria in a favorable environment for the growth of microorganisms, while the coated filter successfully suppressed biofilm development.

摘要

空气过滤器可以有效地过滤外部污染物,包括致病的生物气溶胶;然而,它们也充当了营养有机污染物中捕获的致病细菌的培养场所。尽管许多研究人员已经将各种抗菌涂层应用于过滤器,但涂层应用不可避免地会增加压降,导致净化系统效率低下且能耗高。在这里,我们报告了一种简单的纳米结构氧化锌 (ZnO) 涂层技术,该技术可使聚丙烯无纺过滤器具有卓越的抗菌、防污和抗生物膜性能,而不会增加额外的压降。对于空气动力学涂层设计,过滤器直接浸入低浓度前体溶液中,根据流体动力学使 ZnO 溶胶-凝胶颗粒在过滤器纤维上沉淀。前体浓度会影响所制备涂层的表面拓扑结构和性能。0.07 M 的前体溶液产生了一种无压力增加的玫瑰状纳米结构涂层。大的比表面积和疏水性表面有效地杀死并排斥了附着的细菌。结果,裸露的过滤器在有利于微生物生长的环境中促进了表面细菌的生长和随后的生物膜形成,而涂层过滤器成功地抑制了生物膜的发展。

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