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用于修复污染废水和土壤环境的生物炭基复合材料:挑战与前景

Biochar-based composites for remediation of polluted wastewater and soil environments: Challenges and prospects.

作者信息

Issaka Eliasu, Fapohunda Funmilayo Omotoyosi, Amu-Darko Jesse Nii Okai, Yeboah Linda, Yakubu Salome, Varjani Sunita, Ali Nisar, Bilal Muhammad

机构信息

School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang, 212013, PR China.

School of Life Sciences, Jiangsu University, Zhenjiang, 212013, PR China.

出版信息

Chemosphere. 2022 Jun;297:134163. doi: 10.1016/j.chemosphere.2022.134163. Epub 2022 Feb 28.

Abstract

Pharmaceuticals, heavy metals, pesticides, and dyes are the main environmental contaminants that have serious effects on both land and aquatic lives and necessitate the development of effective methods to mitigate these issues. Although some conventional methods are in use to tackle soil contamination, but biochar and biochar-based composites represent a reliable and sustainable means to deal with a spectrum of toxic organic and inorganic pollutants from contaminated environments. The capacity of biochars and derived constructs to remediate inorganic dyes, pesticides, insecticides, heavy metals, and pharmaceuticals from environmental matrices is attributed to their extensive surface area, surface functional groups, pore size distribution, and high sorption capability of these pollutants in water and soil environments. Application conditions, biochar feedstock, pyrolysis conditions and precursor materials are the factors that influence the capacity and functionality of biochar to adsorb pollutants from wastewater and soil. These factors, when improved, can benefit biochar in agrochemical and heavy metal remediation from various environments. However, the processes involved in biochar production and their influence in enhancing pollutant sequestration remain unclear. Therefore, this paper throws light on the current strategies, operational conditions, and sequestration performance of biochar and biochar-based composites for agrochemical and heavy metal in soil and water environments. The main challenges associated with biochar preparation and exploitation, toxicity evaluation, research directions and future prospects for biochar in environmental remediation are also outlined.

摘要

制药、重金属、农药和染料是主要的环境污染物,对陆地和水生生物都有严重影响,因此有必要开发有效的方法来缓解这些问题。尽管一些传统方法被用于处理土壤污染,但生物炭和基于生物炭的复合材料是处理受污染环境中一系列有毒有机和无机污染物的可靠且可持续的手段。生物炭及其衍生结构从环境基质中修复无机染料、农药、杀虫剂、重金属和药物的能力归因于它们的大表面积、表面官能团、孔径分布以及这些污染物在水和土壤环境中的高吸附能力。应用条件、生物炭原料、热解条件和前驱体材料是影响生物炭从废水和土壤中吸附污染物的能力和功能的因素。这些因素得到改善后,可使生物炭在各种环境中的农用化学品和重金属修复方面发挥作用。然而,生物炭生产所涉及的过程及其对增强污染物固存的影响仍不清楚。因此,本文阐明了生物炭和基于生物炭的复合材料在土壤和水环境中对农用化学品和重金属的当前策略、操作条件和固存性能。还概述了与生物炭制备与开发、毒性评估、生物炭在环境修复中的研究方向和未来前景相关的主要挑战。

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