Removal and Degradation of Microplastics Using the Magnetic and Nanozyme Activities of Bare Iron Oxide Nanoaggregates.

Removal and degradation of microplastics are often carried out separately. In this work, hydrophilic bare Fe O nanoaggregates allowed efficient removal of the most common microplastics including high-density polyethylene, polypropylene, polyvinyl chloride, polystyrene, and polyethylene terephthalate. Full extraction was achieved using Fe O at 1 % of the mass of microplastics. Hydrogen bonding is the main force for the adsorption of Fe O . Unlike the more commonly used hydrophobically modified Fe O nanoparticles, the bare Fe O benefitted from the peroxidase-like activity of its exposed surface, enabling further catalytic degradation of microplastics with nearly 100 % efficiency and easy recovery of the Fe O .