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基于 g-C N 的纳米材料的不同维度、形态进展及其在能量转换和存储方面的工程应用。

Different Dimensionalities, Morphological Advancements and Engineering of g-C N -Based Nanomaterials for Energy Conversion and Storage.

机构信息

College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, 321004, Zhejiang PR, China.

College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004, China.

出版信息

Chem Rec. 2023 May;23(5):e202200171. doi: 10.1002/tcr.202200171. Epub 2023 Apr 17.

Abstract

Graphitic carbon nitride (g-C N ) has gained tremendous interest in the sector of power transformation and retention, because of its distinctive stacked composition, adjustable electronic structure, metal-free feature, superior thermodynamic durability, and simple availability. Furthermore, the restricted illumination and extensive recombination of photoexcitation electrons have inhibited the photocatalytic performance of pure g-C N . The dimensions of g-C N may impact the field of electronics confinement; as a consequence, g-C N with varying dimensions shows unique features, making it appropriate for a number of fascinating uses. Even if there are several evaluations emphasizing on the fabrication methods and deployments of g-C N , there is certainly an insufficiency of a full overview, that exhaustively depicts the synthesis and composition of diverse aspects of g-C N . Consequently, from the standpoint of numerical simulations and experimentation, several legitimate methodologies were employed to deliberately develop the photocatalyst and improve the optimal result, including elements loading, defects designing, morphological adjustment, and semiconductors interfacing. Herein, this evaluation initially discusses different dimensions, the physicochemical features, modifications and interfaces design development of g-C N . Emphasis is given to the practical design and development of g-C N for the various power transformation and inventory applications, such as photocatalytic H evolution, photoreduction of CO source, electrocatalytic H evolution, O evolution, O reduction, alkali-metal battery cells, lithium-ion batteries, lithium-sulfur batteries, and metal-air batteries. Ultimately, the current challenges and potential of g-C N for fuel transformation and retention activities are explored.

摘要

石墨相氮化碳(g-C3N4)因其独特的堆叠结构、可调谐的电子结构、无金属特性、优越的热力学稳定性和简单易得性,在能量转换和存储领域引起了极大的关注。此外,有限的光照和光激发电子的广泛复合抑制了纯 g-C3N4 的光催化性能。g-C3N4 的尺寸可能会影响电子限制领域;因此,具有不同尺寸的 g-C3N4 表现出独特的特性,使其适用于许多迷人的用途。尽管有许多评估强调了 g-C3N4 的制造方法和应用部署,但肯定存在一个不足,即没有全面的概述,详尽地描述 g-C3N4 的各个方面的合成和组成。因此,从数值模拟和实验的角度来看,采用了几种合理的方法来有目的地开发光催化剂并改善最佳结果,包括元素负载、缺陷设计、形态调整和半导体界面。在此,本文首先讨论了不同维度、g-C3N4 的物理化学特性、修饰和界面设计开发。重点介绍了 g-C3N4 在各种能量转换和存储应用中的实际设计和开发,例如光催化 H2 析出、CO 源光还原、电催化 H2 析出、O2 析出、O2 还原、碱金属电池、锂离子电池、锂硫电池和金属-空气电池。最后,探讨了 g-C3N4 在燃料转化和保留活性方面的当前挑战和潜力。

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