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基于导电聚合物的磁性纳米吸附剂在染料和重金属去除方面的最新进展:制备、应用及展望。

Recent advances in conducting polymer-based magnetic nanosorbents for dyes and heavy metal removal: fabrication, applications, and perspective.

机构信息

Department of Chemistry, GLA University, Mathura, 281406, UP, India.

Department of Chemical Engineering, Malaviya National Institute of Technology, Jaipur, India.

出版信息

Environ Sci Pollut Res Int. 2023 Jun;30(29):73031-73060. doi: 10.1007/s11356-023-27458-4. Epub 2023 May 17.

Abstract

Globally, treating and disposing of industrial pollutants is a techno-economic challenge. Industries' large production of harmful heavy metal ions (HMIs) and dyes and inappropriate disposal worsen water contamination. Much attention is required on the development of efficient and cost-effective technologies and approaches for removing toxic HMIs and dyes from wastewater as they pose a severe threat to public health and aquatic ecosystems. Due to the proven superiority of adsorption over other alternative methods, various nanosorbents have been developed for the efficient removal of HMIs and dyes from wastewater and aqueous solutions. Being a good adsorbent, conducting polymer-based magnetic nanocomposites (CP-MNCPs) has drawn more attention for HMIs and dye removal. Conductive polymers' pH-responsiveness makes CP-MNCP ideal for wastewater treatment. The composite material absorbed dyes and/or HMIs from contaminated water could be removed by changing the pH. Here, we review the production strategies and applications of CP-MNCPs for HMIs and dye removal. The review also sheds light on the adsorption mechanism, adsorption efficiency, kinetic and adsorption models, and regeneration capacity of the various CP-MNCPs. To date, various modifications to conducting polymers (CPs) have been explored to improve the adsorption properties. It is evident from the literature survey that the combination of SiO, graphene oxide (GO), and multi-walled carbon nanotubes (MWCNTs) with CPs-MNCPs enhances the adsorption capacity of nanocomposites to a large extent, so future research should lean toward the development of cost-effective hybrid CPs-nanocomposites.

摘要

从全球范围来看,处理和处置工业污染物是一项技术和经济上的挑战。工业生产大量有害的重金属离子(HMIs)和染料,以及不当的处理方式,使水污染问题更加严重。需要高度关注开发高效、经济实用的技术和方法,以去除废水中的有毒 HMIs 和染料,因为它们对公众健康和水生生态系统构成了严重威胁。由于吸附相对于其他替代方法具有明显的优越性,因此已经开发了各种纳米吸附剂,用于从废水中高效去除 HMIs 和染料。作为一种良好的吸附剂,基于导电聚合物的磁性纳米复合材料(CP-MNCPs)在去除 HMIs 和染料方面引起了更多关注。导电聚合物的 pH 响应特性使 CP-MNCP 成为废水处理的理想选择。复合材料从受污染的水中吸附染料和/或 HMIs 后,可以通过改变 pH 值将其去除。在这里,我们综述了 CP-MNCPs 用于去除 HMIs 和染料的生产策略和应用。综述还介绍了各种 CP-MNCPs 的吸附机制、吸附效率、动力学和吸附模型以及再生能力。迄今为止,已经探索了各种对导电聚合物(CPs)的改性方法,以改善吸附性能。从文献综述中可以明显看出,SiO、氧化石墨烯(GO)和多壁碳纳米管(MWCNTs)与 CPs-MNCPs 的结合在很大程度上提高了纳米复合材料的吸附能力,因此未来的研究应该倾向于开发具有成本效益的混合 CPs-纳米复合材料。

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