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基质中碳点的荧光和余辉研究的最新进展。

Recent advances in fluorescence and afterglow of CDs in matrices.

作者信息

Fu Qiang, Lu Kangzhi, Sun Shouhong, Dong Zhanhua

机构信息

College of Engineering, Qufu Normal University, Rizhao, Shandong, 276826, People's Republic of China.

出版信息

Nanoscale Horiz. 2024 Jun 24;9(7):1072-1098. doi: 10.1039/d4nh00093e.

Abstract

Carbon dots (CDs) are novel nanomaterials with dimensions less than 10 nm that have attracted much attention due to their outstanding optical properties. However, the development of solid-state fluorescence and afterglow methods has been relatively slow, although the properties of these materials under liquid conditions have been extensively studied. In recent years, embedding CDs in a matrix has been shown to prevent aggregation quenching and inhibit nonradiative transitions, thus realizing solid-state fluorescence and afterglow, which has greatly broadened the research and application areas of CDs. In terms of hydrogen bonding, ionic bonding, covalent bonding and spatial confinement, the interactions between CDs and matrices can effectively realize and improve the solid-state fluorescence and afterglow effects of CDs. Recent applications of CDs in matrices in optoelectronics, information security, sensing, biotherapeutics and imaging are also summarized. Finally, we summarize the challenges and developments of CDs in matrices.

摘要

碳点(CDs)是尺寸小于10纳米的新型纳米材料,因其出色的光学性能而备受关注。然而,尽管这些材料在液体条件下的性质已得到广泛研究,但固态荧光和余辉方法的发展相对缓慢。近年来,将碳点嵌入基质已被证明可以防止聚集猝灭并抑制非辐射跃迁,从而实现固态荧光和余辉,这极大地拓宽了碳点的研究和应用领域。在氢键、离子键、共价键和空间限制方面,碳点与基质之间的相互作用可以有效地实现和改善碳点的固态荧光和余辉效应。本文还总结了碳点在基质中在光电子学、信息安全、传感、生物治疗和成像方面的最新应用。最后,我们总结了碳点在基质中的挑战和发展情况。

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