Lu Chenxiang, Xu Jiawei, Song Zhe, Zhu Guoqin, Dai Zhenya
Department of Medicinal Chemistry, School of Pharmacy, China Pharmaceutical University 24 Tongjiaxiang Nanjing, 210009 P. R. China.
China Pharmaceutical University Center for Analysis and Testing 24 Tongjiaxiang 210009 P. R. China
RSC Adv. 2025 Feb 6;15(6):4000-4013. doi: 10.1039/d4ra07451c.
We developed a novel fluorescent probe featuring excited-state intramolecular proton transfer (ESIPT) and aggregation-induced emission (AIE) effects, which displayed dual-channel fluorescence emission. The probe detected both Co and HClO with naked eye under daylight as well as through a fluorescence spectrophotometer. The probe exhibited a low detection limit for Co at 2.823 μM, while the detection limit for HClO was 11.55 μM. When the probe (10 μM) was mixed with Co, the fluorescence intensity at 556 nm rapidly decreased within 10 minutes and stabilized after 40 minutes, while for HClO, it took 960 min to observe the same decrease in intensity within 960 min. The probe (10 μM) achieved naked-eye detection of Co recognition under daylight; however, achieving naked-eye detection of HClO under daylight necessitated higher concentrations (500 μM). Thus, this probe shows promising potential for environmental monitoring and water quality detection.
我们开发了一种具有激发态分子内质子转移(ESIPT)和聚集诱导发光(AIE)效应的新型荧光探针,该探针具有双通道荧光发射。该探针在日光下以及通过荧光分光光度计均可肉眼检测钴和次氯酸。该探针对钴的检测限低至2.823 μM,而对次氯酸的检测限为11.55 μM。当探针(10 μM)与钴混合时,556 nm处的荧光强度在10分钟内迅速下降,并在40分钟后稳定下来,而对于次氯酸,在960分钟内观察到相同强度下降则需要960分钟。该探针(10 μM)在日光下实现了对钴识别的肉眼检测;然而,要在日光下实现对次氯酸的肉眼检测则需要更高的浓度(500 μM)。因此,该探针在环境监测和水质检测方面显示出广阔的应用前景。