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聚酯化学回收的最新进展。

Recent advances in the chemical recycling of polyesters.

作者信息

Wang Sheng, Li Jing, Li Xiaohong, Tu Yingfeng

机构信息

Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

Key Laboratory of Ionic Rare Resources and Environment of Ministry of Natural Resources, Jiangxi College of Applied Technology, Ganzhou 341000, China.

出版信息

Fundam Res. 2024 Jun 4;5(3):935-950. doi: 10.1016/j.fmre.2024.05.014. eCollection 2025 May.

Abstract

Whilst polymers have played a significant role in the development of modern society, a rapid growth of polymer waste is disadvantageously influencing communities and ecosystems across the world. Constructing a closed-loop life cycle of polymer materials is urgently in demand. Chemical recycling of polyesters, which can be recovered to the pristine monomers or transformed to other value-added products, has been considered as an appealing recycling approach to circular polymer economy and attracted enormous attention in the last several years. This review highlights some recent progress in the chemical recycling of diverse polyesters, including commercialized poly(lactic acid), poly(-caprolactone), poly(ethylene terephthalate), as well as various novel chemically recyclable polyesters and polycarbonates. Eventually, based on these technological developments, we discuss the remaining challenges and identify promising research opportunities, providing insights into future directions for achieving a genuine closed-loop polymer economy.

摘要

尽管聚合物在现代社会的发展中发挥了重要作用,但聚合物废弃物的快速增长正给世界各地的社区和生态系统带来不利影响。构建聚合物材料的闭环生命周期迫在眉睫。聚酯的化学循环利用,即将其回收为原始单体或转化为其他增值产品,被认为是实现循环聚合物经济的一种有吸引力的回收方法,并在过去几年中引起了广泛关注。本文综述了各种聚酯化学循环利用的一些最新进展,包括商业化的聚乳酸、聚己内酯、聚对苯二甲酸乙二酯,以及各种新型的可化学循环利用的聚酯和聚碳酸酯。最后,基于这些技术发展,我们讨论了仍然存在的挑战,并确定了有前景的研究机会,为实现真正的闭环聚合物经济的未来方向提供了见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ddb/12167880/bb1c31980768/ga1.jpg

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