简便介孔 BODIPY 环化反应及对水中次氯酸盐的选择性传感。
Facile meso-BODIPY annulation and selective sensing of hypochlorite in water.
机构信息
Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS).
出版信息
Org Lett. 2014 Jan 17;16(2):520-3. doi: 10.1021/ol403405n. Epub 2013 Dec 26.
PMID:24369849
Abstract
Annulated BODIPY chalcogenide (Se, Te) systems were synthesized from their respective bis(o-formylphenyl)dichalcogenide intermediates. The annulated BODIPY selenide product was confirmed by X-ray diffraction. The red-shifted telluride version was found to be sensitive and selective for hypochlorite detection, reversible upon treatment with biothiols.
摘要
环状 BODIPY 硫属化物（Se、Te）系统是由其各自的双（邻甲酰基苯基）二硫属化物中间体合成的。环状 BODIPY 硒化物产物通过 X 射线衍射得到证实。发现红色位移的碲化物版本对次氯酸盐检测具有灵敏性和选择性，并且可以通过生物硫醇处理进行可逆反应。
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