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基于共轭吡唑席夫碱的新型铝离子开启型荧光探针

Novel Turn-on Fluorescence Probes for Al Based on Conjugated Pyrazole Schiff Base.

作者信息

Wang Fanwei, Duan Hongdong, Xing Dianxiang, Yang Geng

机构信息

Department of Chemical and Pharmaceutical Engineering, Qilu University of Technology, Jinan, Shandong, 250353, People's Republic of China.

出版信息

J Fluoresc. 2017 Sep;27(5):1721-1727. doi: 10.1007/s10895-017-2110-6. Epub 2017 May 11.

Abstract

One novel turn-on fluorescence probe founded on conjugated pyrazole Schiff base for detecting Al was invented. The UV-vis and fluorescence spectrometer were employed to explore optical properties of this probe. The results got from those experiments indicated that this fluorescence probe manifested excellent sensitivity and selectivity for Al compared with other cations examined(Ag, Co, Mg, Cu, Ni, Pb,and Zn). In addition, this probe displayed a more rapid response and remained stable between pH 6 and 9 by investigating the fluorescence intensity under different response time and various pH values. Remarkably, the detection limit for Al could lower to 1.0×10M. Therefore, the probe could be potentially applied to the environment for the detection of Al, and the availability in biological range of pH that could be further studied to make this probe apply to biological systems in the future.

摘要

一种基于共轭吡唑席夫碱的新型用于检测铝的开启型荧光探针被发明。利用紫外可见光谱仪和荧光光谱仪探究该探针的光学性质。这些实验得到的结果表明,与所检测的其他阳离子(银、钴、镁、铜、镍、铅和锌)相比,该荧光探针对铝表现出优异的灵敏度和选择性。此外,通过研究不同响应时间和各种pH值下的荧光强度,该探针显示出更快的响应,并在pH 6至9之间保持稳定。值得注意的是,铝的检测限可低至1.0×10M。因此,该探针有可能应用于环境中铝的检测,其在生物适用pH范围内的可用性可进一步研究,以便未来使该探针应用于生物系统。

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