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香豆素并香豆素类化合物概述:合成、光物理性质及其应用。

Overview of coumarin-fused-coumarins: synthesis, photophysical properties and their applications.

机构信息

Applied Organic Chemistry Group, Chemical Science and Technology Division, CSIR-North East Institute of Science and Technology, Jorhat 785006, Assam, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, U.P. 201002, India.

出版信息

Org Biomol Chem. 2021 Dec 22;20(1):55-72. doi: 10.1039/d1ob01876k.

Abstract

Coumarin-fused-coumarins have attracted significant attention in the scientific world owing to their boundless applications in interdisciplinary areas. Various synthetic pathways have been developed to construct novel coumarin-fused-coumarin analogues by the fusion of modern methodologies with a classical Pechmann reaction or Knoevenagel condensation. Owing to their extended molecular framework, they possess interesting photophysical properties depending on the fused coumarin ring systems. This review highlights previously published reports on the synthetic strategies for structurally diverse coumarin-fused-coumarins. Furthermore, the scope of the synthesized biscoumarin-fused entities is described by highlighting their photophysical properties and applications.

摘要

香豆素稠合香豆素由于其在跨学科领域的广泛应用而引起了科学界的极大关注。各种合成途径已经被开发出来,通过将现代方法与经典的 Pechmann 反应或 Knoevenagel 缩合反应相结合,构建新型香豆素稠合香豆素类似物。由于其扩展的分子骨架,它们具有有趣的光物理性质,这取决于稠合的香豆素环系统。这篇综述重点介绍了以前关于结构多样的香豆素稠合香豆素的合成策略的报道。此外,通过突出它们的光物理性质和应用,描述了合成的双香豆素稠合实体的范围。

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