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基于高分辨率X射线衍射的纳米结构半导体材料与器件中的晶格应变和缺陷分析:理论与实践层面

Lattice Strain and Defects Analysis in Nanostructured Semiconductor Materials and Devices by High-Resolution X-Ray Diffraction: Theoretical and Practical Aspects.

作者信息

Dolabella Simone, Borzì Aurelio, Dommann Alex, Neels Antonia

机构信息

Center for X-ray Analytics, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, Dübendorf, CH-8600, Switzerland.

Department of Chemistry, University of Fribourg, Chemin du Musée 9, Fribourg, 1700, Switzerland.

出版信息

Small Methods. 2022 Feb;6(2):e2100932. doi: 10.1002/smtd.202100932. Epub 2021 Dec 23.

Abstract

The reliability of semiconductor materials with electrical and optical properties are connected to their structures. The elastic strain field and tilt analysis of the crystal lattice, detectable by the variation in position and shape of the diffraction peaks, is used to quantify defects and investigate their mobility. The exploitation of high-resolution X-ray diffraction-based methods for the evaluation of structural defects in semiconductor materials and devices is reviewed. An efficient and non-destructive characterization is possible for structural parameters such as, lattice strain and tilt, layer composition and thickness, lattice mismatch, and dislocation density. The description of specific experimental diffraction geometries and scanning methods is provided. Today's X-ray diffraction based methods are evaluated and compared, also with respect to their applicability limits. The goal is to understand the close relationship between lattice strain and structural defects. For different material systems, the appropriate analytical methods are highlighted.

摘要

具有电学和光学特性的半导体材料的可靠性与其结构相关。通过衍射峰位置和形状的变化可检测到的晶格弹性应变场和倾斜分析,用于量化缺陷并研究其迁移率。本文综述了利用基于高分辨率X射线衍射的方法来评估半导体材料和器件中的结构缺陷。对于诸如晶格应变和倾斜、层组成和厚度、晶格失配以及位错密度等结构参数,可以进行高效且无损的表征。文中提供了特定实验衍射几何结构和扫描方法的描述。对当今基于X射线衍射的方法进行了评估和比较,同时也考虑了它们的适用范围。目的是了解晶格应变与结构缺陷之间的紧密关系。针对不同的材料体系,突出了合适的分析方法。

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