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噻唑基比色和荧光化学传感器用于重金属离子检测的研究综述。

A Review on Thiazole Based Colorimetric and Fluorimetric Chemosensors for the Detection of Heavy Metal Ions.

机构信息

Department of Chemistry, College of Science and Arts, Najran University, Najran, Saudi Arabia.

Promising Centre for Sensors and Electronic Devices (PCSED), Najran University, Najran, Saudi Arabia.

出版信息

Crit Rev Anal Chem. 2024;54(8):2689-2713. doi: 10.1080/10408347.2023.2197073. Epub 2023 Apr 8.

Abstract

Thiazole and its derivatives play an important role in biological and non-biological fields due to several structural and electronic behaviors associated with it. Thiazole derivatives act as chemosensors because they formed metal complexes upon interacting with various heavy metal ions like Cd, Co, Cr, Fe, Ag, Al, Cu, Pd, Hg, Ni, Ga, In, Sn, Pb, Zn as well as other cations. These metal ions are of prime importance from the environmental point of view with high. This review article focuses on the thiazole-based colorimetric as well as fluorometric sensor for the recognition of different heavy metal cations in various specimens like agricultural, biological, and environmental. It also summarizes the binding stoichiometry, detection limit, pH, structure, and practical application of the reported thiazole-based chemosensors. Further, the sensing performances, have been discussed and compared with some reported organic sensors.

摘要

噻唑及其衍生物由于与其相关的几种结构和电子行为,在生物和非生物领域中起着重要作用。噻唑衍生物作为化学传感器,因为它们与各种重金属离子如 Cd、Co、Cr、Fe、Ag、Al、Cu、Pd、Hg、Ni、Ga、In、Sn、Pb、Zn 以及其他阳离子相互作用时形成金属配合物。这些金属离子从环境角度来看非常重要,因为它们的浓度很高。本文综述了基于噻唑的比色和荧光传感器,用于识别各种样品中的不同重金属阳离子,如农业、生物和环境。它还总结了所报道的基于噻唑的化学传感器的结合化学计量学、检测限、pH 值、结构和实际应用。此外,还讨论并比较了噻唑基传感器的传感性能与一些已报道的有机传感器。

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