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不同的风化条件会影响口罩释放微塑料。

Different weathering conditions affect the release of microplastics by masks.

机构信息

College of Urban Construction, Nanjing Tech University, Nanjing, 211800, China.

出版信息

Environ Sci Pollut Res Int. 2023 May;30(24):66102-66112. doi: 10.1007/s11356-023-27116-9. Epub 2023 Apr 25.

Abstract

A generation of microplastics caused by improper disposal of disposable masks has become a non-negligible environmental concern. In order to investigate the degradation mechanisms of masks and the release of microplastics under different environmental conditions, the masks are placed in 4 common environments. After 30 days of weathering, the total amount and release kinetics of microplastics released from different layers of the mask were studied. The chemical and mechanical properties of the mask were also discussed. The results showed that the mask released 25141±3543 particles/mask into the soil, which is much more than the sea and river water. The release kinetics of microplastics fit the Elovich model better. All samples correspond to the release rate of microplastics from fast to slow. Experiments show that the middle layer of the mask is released more than the other layers, and the amount of release was highest in the soil. And the tensile capacity of the mask is negatively correlated with its ability to release microplastics in the following order, which are soil > seawater > river > air > new masks. In addition, during the weathering process, the C-C/C-H bond of the mask was broken.

摘要

由一次性口罩不当处理而产生的新一代微塑料已成为不可忽视的环境关注点。为了研究口罩在不同环境条件下的降解机制和微塑料的释放情况,将口罩放置在 4 种常见环境中。经过 30 天的风化后,研究了不同口罩层释放的微塑料的总量和释放动力学。还讨论了口罩的化学和机械性能。结果表明,口罩向土壤中释放了 25141±3543 个/口罩的微塑料,这比海水和河水多得多。微塑料的释放动力学更符合 Elovich 模型。所有样本均对应于从快到慢释放微塑料的释放率。实验表明,口罩的中间层释放的微塑料比其他层多,在土壤中的释放量最高。并且口罩的拉伸能力与释放微塑料的能力呈负相关,按顺序依次为,土壤>海水>河水>空气>新口罩。此外,在风化过程中,口罩的 C-C/C-H 键断裂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00e8/10127988/dd68392b8a94/11356_2023_27116_Fig1_HTML.jpg

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