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微塑料指数——如何预测微塑料的形成?

Microplastic Index-How to Predict Microplastics Formation?

作者信息

Boersma Arjen, Grigoriadi Kalouda, Nooijens Merel G A, Henke Sieger, Kooter Ingeborg M, Parker Luke A, Dortmans Ardi, Urbanus Jan Harm

机构信息

TNO, HTC 25, 5656 AE Eindhoven, The Netherlands.

TNO, Princetonlaan 6-8, 3584 CB Utrecht, The Netherlands.

出版信息

Polymers (Basel). 2023 May 4;15(9):2185. doi: 10.3390/polym15092185.

Abstract

The presence of microplastics in environmental compartments is generally recognized as a (potential) health risk. Many papers have been published on the abundance of microplastics at various locations around the globe, but only limited knowledge is available on possible mitigation routes. One of the mitigation routes is based on the choice of plastic materials used for products that may unintentionally end up in the environment. As a first approach, this paper presents a method to calculate the tendency of polymers to form microplastics, based on their mechanical and physical properties. A MicroPlastic Index (MPI) that correlates the microplastic formation to polymer properties is defined for both impact and wear of polymers via a theoretical particle size and the energy required to form these particles. A first comparison between calculated and experimental particle size is included. The MPI for impact and wear follow the same trend. Finally, these MPIs are correlated to the respective abundance of the microplastics in the environment, corrected for global production of the corresponding polymers: the higher the MPI, the more microplastics are found in the environment. Thus, the MPI can be used as a basis for choice or redesign of polymers to reduce microplastic formation.

摘要

环境介质中微塑料的存在通常被认为是一种(潜在的)健康风险。关于全球各地不同位置微塑料的丰度,已经发表了许多论文,但对于可能的缓解途径,人们了解有限。其中一种缓解途径基于对可能无意间进入环境的产品所使用塑料材料的选择。作为第一步,本文提出了一种基于聚合物的机械和物理性质来计算聚合物形成微塑料倾向的方法。通过理论粒径以及形成这些颗粒所需的能量,为聚合物的冲击和磨损定义了一个将微塑料形成与聚合物性质相关联的微塑料指数(MPI)。文中包含了计算粒径与实验粒径的首次比较。聚合物冲击和磨损的MPI呈现相同趋势。最后,这些MPI与环境中微塑料各自的丰度相关联,并根据相应聚合物的全球产量进行了校正:MPI越高,在环境中发现的微塑料就越多。因此,MPI可作为选择或重新设计聚合物以减少微塑料形成的依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c618/10181052/a91d9425cf65/polymers-15-02185-g001.jpg

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