Threshold damage mechanisms in brittle solids and their impact on advanced technologies.

Threshold damage mechanisms in brittle covalent-ionic solids are outlined. Fracture and deformation modes are analyzed in terms of classical contact mechanics. Distinctions are made between brittle, ductile and quasiplastic mechanisms in both axial and translational contact. Special attention is devoted to the relatively unexplored subthreshold region where macrofracture is largely suppressed, a region of increasing relevance in the relentless move toward ever smaller devices and precision shaping technologies in the manufacturing sector. Cross-section micrographic images illustrate the fundamental nature of shear events within the hardness deformation zone responsible for crack initiation and propagation. Basic analytical relations for the strengths of surfaces with contact-induced damage in the postthreshold and subthreshold regions are presented, with emphasis on concept rather than fine detail. Strength data for a prototypical brittle material after sharp-indenter damage are presented to highlight the vital role of microstructure in determining transitions between brittle and quasiplastic responses. Pristine defect-free solids are shown to be highly vulnerable to contact damage, even in the subthreshold region. Heterogeneous solids with granular microstructures have lower initial strengths, but are more flaw tolerant. Brittle solids are also highly susceptible to degradation by surface removal processes in wear and machining settings, to a large extent depending again on microstructure. Implications of these findings concerning advanced technological applications of covalent-ionic solids are discussed.