Lv Shengnan, Zhao Xin, Shi Lei, Zhang Gaokai, Wang Shubo, Kang Weimin, Zhuang Xupin
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China.
School of Textile, Tianjin Polytechnic University, Tianjin 300387, China.
Polymers (Basel). 2018 Sep 6;10(9):996. doi: 10.3390/polym10090996.
Particulate matter (PM) pollution is a serious concern for the environment and public health. To protect indoor air quality, nanofiber filters have been used to coat window screens due to their high PM removal efficiency, transparency and low air resistance. However, these materials have poor mechanical property. In this study, electrostatic induction-assisted solution blowing was used to fabricate polylactide stereocomplex (-PLA), which served as reinforcement to enhance the physical cross-linking point to significantly restrict poly(methyl methacrylate) (PMMA) molecular chain motion and improve the mechanical properties of -PLA/PMMA nanofibers. Moreover, the introduction of -PLA led to the formation of thick/thin composite nanofiber structure, which is beneficial for the mechanical property. Thus, -PLA/PMMA air filters of ~83% transparency with 99.5% PM removal and 140% increase in mechanical properties were achieved when 5 wt % -PLA was added to PMMA. Hence, the addition of -PLA to transparent filters can effectively improve their performance.
颗粒物(PM)污染是环境和公众健康的严重问题。为了保护室内空气质量,纳米纤维过滤器因其对PM的高去除效率、透明度和低空气阻力而被用于涂覆窗纱。然而,这些材料的机械性能较差。在本研究中,采用静电感应辅助溶液吹塑法制备了聚丙交酯立体复合物(-PLA),其作为增强剂以增强物理交联点,从而显著限制聚甲基丙烯酸甲酯(PMMA)分子链的运动并改善-PLA/PMMA纳米纤维的机械性能。此外,-PLA的引入导致形成厚/薄复合纳米纤维结构,这有利于机械性能。因此,当向PMMA中添加5 wt%的-PLA时,可实现透明度约为83%、PM去除率为99.5%且机械性能提高140%的-PLA/PMMA空气过滤器。因此,向透明过滤器中添加-PLA可有效提高其性能。