Dippong Thomas, Levei Erika Andrea, Cadar Oana
Faculty of Science, Technical University of Cluj-Napoca, 430122 Baia Mare, Romania.
National Institute for Research and Development for Optoelectronics INOE 2000, Research Institute for Analytical Instrumentation Subsidiary, 400293 Cluj-Napoca, Romania.
Nanomaterials (Basel). 2021 Jun 13;11(6):1560. doi: 10.3390/nano11061560.
In the last decade, research on the synthesis and characterization of nanosized ferrites has highly increased and a wide range of new applications for these materials have been identified. The ability to tailor the structure, chemical, optical, magnetic, and electrical properties of ferrites by selecting the synthesis parameters further enhanced their widespread use. The paper reviews the synthesis methods and applications of MFeO (M = Co, Cu, Mn, Ni, Zn) nanoparticles, with emphasis on the advantages and disadvantages of each synthesis route and main applications. Along with the conventional methods like sol-gel, thermal decomposition, combustion, co-precipitation, hydrothermal, and solid-state synthesis, several unconventional methods, like sonochemical, microwave assisted combustion, spray pyrolysis, spray drying, laser pyrolysis, microemulsion, reverse micelle, and biosynthesis, are also presented. MFeO (M = Co, Cu, Mn, Ni, Zn) nanosized ferrites present good magnetic (high coercivity, high anisotropy, high Curie temperature, moderate saturation magnetization), electrical (high electrical resistance, low eddy current losses), mechanical (significant mechanical hardness), and chemical (chemical stability, rich redox chemistry) properties that make them suitable for potential applications in the field of magnetic and dielectric materials, photoluminescence, catalysis, photocatalysis, water decontamination, pigments, corrosion protection, sensors, antimicrobial agents, and biomedicine.
在过去十年中,关于纳米铁氧体的合成与表征的研究急剧增加,并且已经确定了这些材料的广泛新应用。通过选择合成参数来定制铁氧体的结构、化学、光学、磁性和电学性质的能力进一步扩大了它们的广泛应用。本文综述了MFeO(M = Co、Cu、Mn、Ni、Zn)纳米颗粒的合成方法和应用,重点介绍了每种合成路线的优缺点以及主要应用。除了溶胶 - 凝胶、热分解、燃烧、共沉淀、水热和固态合成等传统方法外,还介绍了几种非常规方法,如声化学、微波辅助燃烧、喷雾热解、喷雾干燥、激光热解、微乳液、反胶束和生物合成。MFeO(M = Co、Cu、Mn、Ni、Zn)纳米铁氧体具有良好的磁性(高矫顽力、高各向异性、高居里温度、适度饱和磁化强度)、电学(高电阻、低涡流损耗)、机械(显著的机械硬度)和化学(化学稳定性、丰富的氧化还原化学性质)性质,这使得它们适用于磁性和介电材料、光致发光、催化、光催化、水净化、颜料、腐蚀防护、传感器、抗菌剂和生物医学等领域的潜在应用。